eTheses Repository

The effect of hydrogen on palladium-copper based membranes for hydrogen purification

Warren, James Raphael (2012)
M.Res. thesis, University of Birmingham.

Loading
PDF (3227Kb)

Abstract

The use of high purity hydrogen (>99.9999%), refined by palladium based membranes, is critical to the lifetime of PEM fuel cells. The alloy currently used for purification is palladium-silver; which suffers from both low strength and poor resistance to poisoning. Palladium-copper may be a suitable alternative as it has reasonable permeability, particularly at 47 atomic% Pd. The Pd-Cu binary phase system has been studied although around the high permeability region the boundary lines remain unclear. A shift in the observed phase boundary line under hydrogen pressure is noted in the literature although little work to comprehensively study the extent of this effect has been carried out. Variations between the solubility and diffusivity of f.c.c. and b.c.c. grains may also have an effect on the thermal cycling properties of the alloy; potentially reducing membrane selectivity over time. Varying hydrogen content across the membrane is thought to give a structural gradient which could strongly affect the material properties and the optimum operating conditions. In this thesis in-situ XRD and permeability measurements of three Pd-Cu alloys have been performed to investigate the effect that hydrogen overpressure has on the observed phase boundary and optimisation of the membrane operating conditions for permeability.

Type of Work:M.Res. thesis.
Supervisor(s):Fletcher, Sean and Speight, John and Book, David
School/Faculty:Colleges (2008 onwards) > College of Engineering & Physical Sciences
Department:School of Metallurgy and Materials
Subjects:TN Mining engineering. Metallurgy
Institution:University of Birmingham
ID Code:3319
This unpublished thesis/dissertation is copyright of the author and/or third parties. The intellectual property rights of the author or third parties in respect of this work are as defined by The Copyright Designs and Patents Act 1988 or as modified by any successor legislation. Any use made of information contained in this thesis/dissertation must be in accordance with that legislation and must be properly acknowledged. Further distribution or reproduction in any format is prohibited without the permission of the copyright holder.
Export Reference As : ASCII + BibTeX + Dublin Core + EndNote + HTML + METS + MODS + OpenURL Object + Reference Manager + Refer + RefWorks
Share this item :
QR Code for this page

Repository Staff Only: item control page