Development of a novel oxide-oxide ceramic matrix composite for high temperature structural applications

Dearn, Sophie Clare (2015). Development of a novel oxide-oxide ceramic matrix composite for high temperature structural applications. University of Birmingham. Ph.D.

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Abstract

The introduction of ceramic matrix composites (CMCs) for structural applications in the hot section of a gas turbine provides many potential benefits over conventional alloy materials, including facilitating elevated operating temperatures. The development of an oxide-oxide CMC composed of commercially available Nextel 720 (3M) fibres within a porous alumina matrix was presented.

A simple, low cost processing method involving slurry impregnation and subsequent consolidation and densification was developed, facilitating the production of dried pre-impregnated fabric (‘pre-preg’) that can be stored in ambient conditions. Detailed investigation into the effect of three types of PVA binder, the effect of 0-20wt% additions of an alumina precursor (ACH), the influence of a bimodal particle distribution and the effect of sintering at temperatures between 1100 and 1300°C on processing and mechanical properties was completed in order to optimise the material.

The optimised composite material, composed of Nextel 720 fibres within a submicron alumina particle matrix with 10wt% ACH sintered at 1200°C, exhibited mean flexural strength >205MPa, short beam shear strength >12MPa and tensile strength >146MPa. These results were comparable to similar oxide CMCs previously reported, validating this material.

Type of Work:

Thesis (Doctorates > Ph.D.)

Award Type:

Doctorates > Ph.D.

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