High pressure diffraction studies of gallosilicate natrolite: applications to pressure-induced cation trapping

1112 66 2770 9 3973 document 2770 Hill10PhD1.pdf application/pdf 2140ea792d11fcf7812b697550fe1a26 MD5 2431703 2011-07-19 16:29:31 http://etheses.bham.ac.uk//id/eprint/1112/1/Hill10PhD1.pdf 1112 1 1 application/pdf application/pdf en public

Hill10PhD1.pdf

http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7073 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7073 http://eprints.org/relation/hasIndexCodesVersion http://etheses.bham.ac.uk/id/document/7073 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7091 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7091 http://eprints.org/relation/hassmallThumbnailVersion http://etheses.bham.ac.uk/id/document/7091 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7092 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7092 http://eprints.org/relation/haspreviewThumbnailVersion http://etheses.bham.ac.uk/id/document/7092 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7097 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7097 http://eprints.org/relation/hasIndexCodesVersion http://etheses.bham.ac.uk/id/document/7097 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/13706 http://eprints.org/relation/haspreviewThumbnailVersion http://etheses.bham.ac.uk/id/document/13706 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/13706 2772 9 3975 document 2772 Hill10PhD2.pdf application/pdf 1cfcb4e7a5ae544eb85908799c2b59e9 MD5 17377092 2011-07-19 16:29:31 http://etheses.bham.ac.uk//id/eprint/1112/2/Hill10PhD2.pdf 1112 2 2 application/pdf application/pdf en public

Hill10PhD2.pdf

http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7074 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7074 http://eprints.org/relation/hasIndexCodesVersion http://etheses.bham.ac.uk/id/document/7074 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7080 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7080 http://eprints.org/relation/hassmallThumbnailVersion http://etheses.bham.ac.uk/id/document/7080 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7081 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7081 http://eprints.org/relation/haspreviewThumbnailVersion http://etheses.bham.ac.uk/id/document/7081 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7082 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7082 http://eprints.org/relation/hasIndexCodesVersion http://etheses.bham.ac.uk/id/document/7082 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/13707 http://eprints.org/relation/haspreviewThumbnailVersion http://etheses.bham.ac.uk/id/document/13707 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/13707 2775 8 3979 document 2775 Hill10PhD3.pdf application/pdf 2494c13d6336770a8b93c807bf61de4e MD5 16352391 2011-07-19 16:29:33 http://etheses.bham.ac.uk//id/eprint/1112/3/Hill10PhD3.pdf 1112 3 3 application/pdf application/pdf en public

Hill10PhD3.pdf

http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7071 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7071 http://eprints.org/relation/hassmallThumbnailVersion http://etheses.bham.ac.uk/id/document/7071 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7072 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7072 http://eprints.org/relation/haspreviewThumbnailVersion http://etheses.bham.ac.uk/id/document/7072 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7075 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7075 http://eprints.org/relation/hasIndexCodesVersion http://etheses.bham.ac.uk/id/document/7075 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/13708 http://eprints.org/relation/haspreviewThumbnailVersion http://etheses.bham.ac.uk/id/document/13708 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/13708 2777 7 3981 document 2777 Decl_IS_Hill10PhD.pdf application/pdf 4aa9a7904224e5a787cf541c0aa3496d MD5 101159 2011-07-19 16:29:35 http://etheses.bham.ac.uk//id/eprint/1112/4/Decl_IS_Hill10PhD.pdf 1112 4 4 application/pdf application/pdf en staffonly

Decl_IS_Hill10PhD.pdf

http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7076 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7076 http://eprints.org/relation/hasIndexCodesVersion http://etheses.bham.ac.uk/id/document/7076 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7077 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7077 http://eprints.org/relation/hassmallThumbnailVersion http://etheses.bham.ac.uk/id/document/7077 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7078 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7078 http://eprints.org/relation/haspreviewThumbnailVersion http://etheses.bham.ac.uk/id/document/7078 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/7079 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/7079 http://eprints.org/relation/hasIndexCodesVersion http://etheses.bham.ac.uk/id/document/7079 http://eprints.org/relation/hasVolatileVersion http://etheses.bham.ac.uk/id/document/13709 http://eprints.org/relation/haspreviewThumbnailVersion http://etheses.bham.ac.uk/id/document/13709 http://eprints.org/relation/hasVersion http://etheses.bham.ac.uk/id/document/13709 7071 2 9306 document 7071 small.png image/png 50226c3b21ddf4fb1c860297668226a9 MD5 6018 2011-07-19 20:09:44 http://etheses.bham.ac.uk//id/eprint/1112/5/small.png 1112 5 5 image/png thumbnail_small Thumbnail Documents conversion from application/pdf to thumbnail_small en public

small.png

http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2775 http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2775 http://eprints.org/relation/issmallThumbnailVersionOf http://etheses.bham.ac.uk/id/document/2775 7072 2 9307 document 7072 preview.jpg image/jpeg 6db9265f86e23855428a7f62d371235c MD5 20855 2011-07-19 20:09:45 http://etheses.bham.ac.uk//id/eprint/1112/6/preview.jpg 1112 6 6 image/jpeg image/jpeg Thumbnail Documents conversion from application/pdf to thumbnail_preview en public

preview.jpg

http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2775 http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2775 http://eprints.org/relation/ispreviewThumbnailVersionOf http://etheses.bham.ac.uk/id/document/2775 7091 2 9329 document 7091 small.png image/png 35a46e8b975d297ea088f1d012845c8e MD5 3493 2011-07-19 20:11:03 http://etheses.bham.ac.uk//id/eprint/1112/16/small.png 1112 16 16 image/png thumbnail_small Thumbnail Documents conversion from application/pdf to thumbnail_small en public

small.png

http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2770 http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2770 http://eprints.org/relation/issmallThumbnailVersionOf http://etheses.bham.ac.uk/id/document/2770 7080 2 9316 document 7080 small.png image/png 0ad71b0e1d30ca7cdedc57577bcbb14a MD5 5913 2011-07-19 20:10:18 http://etheses.bham.ac.uk//id/eprint/1112/13/small.png 1112 13 13 image/png thumbnail_small Thumbnail Documents conversion from application/pdf to thumbnail_small en public

small.png

http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2772 http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2772 http://eprints.org/relation/issmallThumbnailVersionOf http://etheses.bham.ac.uk/id/document/2772 7075 2 9311 document 7075 indexcodes.txt text/plain 2bb5edd0840550286fbd9b7de7fa284f MD5 24069 2011-07-19 20:10:01 http://etheses.bham.ac.uk//id/eprint/1112/9/indexcodes.txt 1112 9 9 text/plain indexcodes Generate index codes conversion from application/pdf to indexcodes en public

indexcodes.txt

http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2775 http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2775 http://eprints.org/relation/isIndexCodesVersionOf http://etheses.bham.ac.uk/id/document/2775 7078 2 9314 document 7078 preview.jpg image/jpeg ef886618ca7971efabceecf6f73acc74 MD5 44709 2011-07-19 20:10:05 http://etheses.bham.ac.uk//id/eprint/1112/11/preview.jpg 1112 11 11 image/jpeg image/jpeg Thumbnail Documents conversion from application/pdf to thumbnail_preview en staffonly

preview.jpg

http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2777 http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2777 http://eprints.org/relation/ispreviewThumbnailVersionOf http://etheses.bham.ac.uk/id/document/2777 7077 2 9313 document 7077 small.png image/png 642b40603b3fcab4d53c1a7bb2d6381a MD5 11023 2011-07-19 20:10:05 http://etheses.bham.ac.uk//id/eprint/1112/10/small.png 1112 10 10 image/png thumbnail_small Thumbnail Documents conversion from application/pdf to thumbnail_small en staffonly

small.png

http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2777 http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2777 http://eprints.org/relation/issmallThumbnailVersionOf http://etheses.bham.ac.uk/id/document/2777 7079 2 9315 document 7079 indexcodes.txt text/plain 53b4007f183175ff7e4bda8278140eec MD5 1507 2011-07-19 20:10:09 http://etheses.bham.ac.uk//id/eprint/1112/12/indexcodes.txt 1112 12 12 text/plain indexcodes Generate index codes conversion from application/pdf to indexcodes en staffonly

indexcodes.txt

http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2777 http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2777 http://eprints.org/relation/isIndexCodesVersionOf http://etheses.bham.ac.uk/id/document/2777 7081 2 9317 document 7081 preview.jpg image/jpeg f1c5775767f91ede128ab624b7d6645d MD5 20245 2011-07-19 20:10:20 http://etheses.bham.ac.uk//id/eprint/1112/14/preview.jpg 1112 14 14 image/jpeg image/jpeg Thumbnail Documents conversion from application/pdf to thumbnail_preview en public

preview.jpg

http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2772 http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2772 http://eprints.org/relation/ispreviewThumbnailVersionOf http://etheses.bham.ac.uk/id/document/2772 7082 2 9319 document 7082 indexcodes.txt text/plain bd80aa129ac31ce03b6ae3567d7d726d MD5 23466 2011-07-19 20:10:28 http://etheses.bham.ac.uk//id/eprint/1112/15/indexcodes.txt 1112 15 15 text/plain indexcodes Generate index codes conversion from application/pdf to indexcodes en public

indexcodes.txt

http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2772 http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2772 http://eprints.org/relation/isIndexCodesVersionOf http://etheses.bham.ac.uk/id/document/2772 7092 2 9330 document 7092 preview.jpg image/jpeg 4d040f6c2d2c0aed507da626ee3d23a4 MD5 13859 2011-07-19 20:11:04 http://etheses.bham.ac.uk//id/eprint/1112/17/preview.jpg 1112 17 17 image/jpeg image/jpeg Thumbnail Documents conversion from application/pdf to thumbnail_preview en public

preview.jpg

http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2770 http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2770 http://eprints.org/relation/ispreviewThumbnailVersionOf http://etheses.bham.ac.uk/id/document/2770 7097 2 9336 document 7097 indexcodes.txt text/plain 6e1bf4064951ca20c85c37083ef1c355 MD5 10909 2011-07-19 20:11:17 http://etheses.bham.ac.uk//id/eprint/1112/18/indexcodes.txt 1112 18 18 text/plain indexcodes Generate index codes conversion from application/pdf to indexcodes en public

indexcodes.txt

http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2770 http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2770 http://eprints.org/relation/isIndexCodesVersionOf http://etheses.bham.ac.uk/id/document/2770 13706 2 20405 document 13706 preview.png image/png 318fcac9bbe5596106e930a7258c3fa5 MD5 16407 2011-07-21 10:52:27 http://etheses.bham.ac.uk//id/eprint/1112/19/preview.png 1112 19 19 image/png image/png en public

preview.png

http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2770 http://eprints.org/relation/ispreviewThumbnailVersionOf http://etheses.bham.ac.uk/id/document/2770 http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2770 13707 2 20408 document 13707 preview.png image/png 43a776a69232cccd30d63d54ec5ecd70 MD5 23417 2011-07-21 10:52:28 http://etheses.bham.ac.uk//id/eprint/1112/20/preview.png 1112 20 20 image/png image/png en public

preview.png

http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2772 http://eprints.org/relation/ispreviewThumbnailVersionOf http://etheses.bham.ac.uk/id/document/2772 http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2772 13708 2 20411 document 13708 preview.png image/png 0edac0778bb6263d4db57bd32d647665 MD5 24000 2011-07-21 10:52:28 http://etheses.bham.ac.uk//id/eprint/1112/21/preview.png 1112 21 21 image/png image/png en public

preview.png

http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2775 http://eprints.org/relation/ispreviewThumbnailVersionOf http://etheses.bham.ac.uk/id/document/2775 http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2775 13709 2 20414 document 13709 preview.png image/png 1f1e5e6afc2851fd16653f4ba4f6ccea MD5 44268 2011-07-21 10:52:28 http://etheses.bham.ac.uk//id/eprint/1112/22/preview.png 1112 22 22 image/png image/png en staffonly

preview.png

http://eprints.org/relation/isVolatileVersionOf http://etheses.bham.ac.uk/id/document/2777 http://eprints.org/relation/ispreviewThumbnailVersionOf http://etheses.bham.ac.uk/id/document/2777 http://eprints.org/relation/isVersionOf http://etheses.bham.ac.uk/id/document/2777 archive 4031 disk0/00/00/11/12 2010-11-22 12:59:03 2019-01-23 09:53:30 2011-07-19 16:29:31 thesis show 0 Hill Gemma Louise Hriljac Joseph A. University of Birmingham High pressure diffraction studies of gallosilicate natrolite: applications to pressure-induced cation trapping unpub QD 10col_ephy The natrolite family of zeolites undergoes volume expansion under pressure. Natrolite itself is a three dimensionally porous zeolite with 8-ring channels. It shows an unusual unit cell volume expansion when under hydrostatic pressure where it undergoes two distinct, reversible phase transitions to paranatrolite and then super-hydrated natrolite. The behaviour of gallosilicate natrolite, a synthetic analogue of the aluminosilicate mineral, was investigated in this thesis. Two forms exist, orthorhombic (as per the mineral) and tetragonal. These two forms have been synthesised and structurally characterised by powder neutron diffraction and synchrotron X-ray diffraction techniques at ambient pressure to elucidate details of the ordering. In addition, high pressure neutron and synchrotron X-ray diffraction data have been collected on both the tetragonal and the orthorhombic forms. These data confirm pressure-induced hydration and pore swelling in both the gallosilicate materials, as seen in the aluminosilicate form but at much lower pressures. The neutron data has also allowed a full study of the changes in hydrogen-bonding in the normal and superhydrated states. The natrolite family will not normally undergo ambient ion-exchange due to the small pores and the strongly bound framework cations. Exploitation of the pressure-induced state offered a high pressure ion-exchange route, with trapping of large exchanged cations upon pressure release. Ion exchange investigations using the aluminosilicate and gallosilicate natrolites have provided the first evidence of high pressure cation trapping. Exposure to a saturated CsCl solution at a pressure of 1 GPa and a temperature of 100°C led to cesium trapping within the framework upon pressure release. Back-exchange treatment in a sodium chloride reflux did not leach the trapped cesium. For the aluminosilicate natrolite up to 33% Na/Cs exchange was trapped within the framework via this high pressure exchange method. 2010-12 2010 graduation eng author unchecked This unpublished thesis/dissertation is copyright of the author and/or third parties. The intellectual property rights of the author or third parties in respect of this work are as defined by The Copyright Designs and Patents Act 1988 or as modified by any successor legislation. Any use made of information contained in this thesis/dissertation must be in accordance with that legislation and must be properly acknowledged. Further distribution or reproduction in any format is prohibited without the permission of the copyright holder. FALSE Nexia Solutions public 384 University of Birmingham School of Chemistry d_ph FALSE epsrc other 2010-12 graduation