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Treatment of endocrine disrupting chemicals using the downflow gas contractor reactor

Althafiri, Faisal S. (2016)
Ph.D. thesis, University of Birmingham.

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Abstract

The photodegradation of the selected steroid hormones, 17β-Estradiol (17β-E2), 17α-Estradiol (17α-E2), Estrone (E1) and Progesterone (PG) in aqueous solutions has been studied using the Downflow Gas Contactor Reactor (DGCR). The performance evaluation of the DGCR as providing an efficient and economical advanced oxidation process (AOP) demonstrated that it can be considered a promising AOP capable of total degradation in a short period of time. A fast and reliable chromatographic method was developed and validated to study the performance of the DGCR down to the ng L–\(^1\) level. Hydrodynamic and mass transfer characteristics of the DGCR were examined extensively, and the optimum operating conditions were identified. The photodegradation process fit well with pseudo-first order kinetics with R\(^2\) ≥ 99%. UV irradiation is the main factor affecting the whole degradation process. The effect of the initial concentration, initial pH, different O2 flowrates, hydrogen peroxide and different combinations of UV systems with the DGCR were all explored to evaluate the photodegradation performance and the removal efficiency. These results show great promise for the DGCR that it can be considered a promising AOP at the industrial scale applications.

Type of Work:Ph.D. thesis.
Supervisor(s):Leeke, Gary and Santos, Regina
School/Faculty:Colleges (2008 onwards) > College of Engineering & Physical Sciences
Department:School of Chemical Engineering
Subjects:QC Physics
QD Chemistry
Institution:University of Birmingham
ID Code:6830
This unpublished thesis/dissertation is copyright of the author and/or third parties. The intellectual property rights of the author or third parties in respect of this work are as defined by The Copyright Designs and Patents Act 1988 or as modified by any successor legislation. Any use made of information contained in this thesis/dissertation must be in accordance with that legislation and must be properly acknowledged. Further distribution or reproduction in any format is prohibited without the permission of the copyright holder.
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