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Ageing of integrated-planar Solid Oxide Fuel Cells

Almutairi, Ghzzai (2013)
Ph.D. thesis, University of Birmingham.

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The ageing of Solid Oxide Fuel Cells (SOFCs) is a key problem because of the requirement of 50,000 hours to their lifetime in many applications. At present, such performance is still not attainable because degradation occurs at more than 1% per thousand hours under practical test conditions. In this thesis, the ageing of the Rolls Royce Fuel Cell Systems (RRFCS)Integrated Planar Solid Oxide Fuel Cell (IP-SOFC) was studied under different operating conditions, especially by accelerated degradation testing (ADT), in order to investigate the fuel cell stability and degradation behaviour under non-steady operating conditions for further improvement of the systems.

This work demonstrates that the long-term durability of the IP-SOFC is very good when pure hydrogen is used as fuel. However, the introducing of even a small amount of methane in fuel has demonstrated the capacity to damage the IP-SOFC through the formation of carbon deposits on the anode surface. Future work is therefore required to identify viable alternative materials and optimal operating conditions.

Type of Work:Ph.D. thesis.
Supervisor(s):Kendall, Kevin and Bujalski, Waldemar and Dhir, Aman
School/Faculty:Colleges (2008 onwards) > College of Engineering & Physical Sciences
Department:School of Engineering
Subjects:TJ Mechanical engineering and machinery
TP Chemical technology
Institution:University of Birmingham
ID Code:4422
This unpublished thesis/dissertation is copyright of the author and/or third parties. The intellectual property rights of the author or third parties in respect of this work are as defined by The Copyright Designs and Patents Act 1988 or as modified by any successor legislation. Any use made of information contained in this thesis/dissertation must be in accordance with that legislation and must be properly acknowledged. Further distribution or reproduction in any format is prohibited without the permission of the copyright holder.
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