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Design of shell-type ligands for luminescent lanthanide complexes

Davies, Dita (2011)
Ph.D. thesis, University of Birmingham.

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Abstract

A series of lanthanide complexes based on tetraphenyl imidodiphosphate ligand have been prepared in order to investigate the ligand ability to act as a sensitiser for f-f based luminescence for the visible and NIR emitting ions. Furthermore, novel bimetallic luminescent lanthanide complexes based on two imidodiphosphate binding sites have been prepared for the examination of dinuclear lanthanide complexes formation. The sensitising properties of the bistpOp have been investigated by luminescence spectroscopy. A new ligand based on biphenyl sensitisers has been developed utilising an imidodiphosphate binding site. The lanthanide complexes have been prepared and their photophysical properties analysed.

Type of Work:Ph.D. thesis.
School/Faculty:Colleges (2008 onwards) > College of Engineering & Physical Sciences
Department:School of Chemistry
Subjects:QD Chemistry
Institution:University of Birmingham
ID Code:1742
This unpublished thesis/dissertation is copyright of the author and/or third parties. The intellectual property rights of the author or third parties in respect of this work are as defined by The Copyright Designs and Patents Act 1988 or as modified by any successor legislation. Any use made of information contained in this thesis/dissertation must be in accordance with that legislation and must be properly acknowledged. Further distribution or reproduction in any format is prohibited without the permission of the copyright holder.
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