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Chemical performance of cement stabilised contaminated clay

John, Unyime Edet (2011)
Ph.D. thesis, University of Birmingham.

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Urban demand has increased the need to redevelop contaminated land. New legislation for land management has actively discouraged previously acceptable dig and dump practices. This has encouraged in-situ remediation approaches, for which stabilisation / solidification (S/S) is particularly suitable for treating metal contamination. However, concerns over long-term effectiveness and durability of S/S needs to addressed, because contamination is contained but not removed. This requires effective chemical assessments to inform design. This study aims to design a suitable method for assessing S/S effectiveness, using a holistic risk based approach, for use during performance based S/S design. The processes that induce containment were evaluated, by assessing the solubility controlling mechanisms, and undertaking geochemical speciation modelling, to determine solubility controlling minerals. These findings can be used at the design stage to engineer S/S application to particular sites, and ensure long-term performance with minimal risk. Evaluations for structural master species (Al, Si, and Ca) and contaminants (Zn\(^2\)\(^+\), Cr\(^3\)\(^+\)) in cement stabilised contaminated kaolin were undertaken. The influences of common soil components (Humic acid and sodium sulphate), and increasing hydration durations were also assessed, to inform containment effectiveness and chemical durability. Findings showed that the assessment method was suitable for chemical characterisation of stabilised matrices, as a tool for informing design and application.

Type of Work:Ph.D. thesis.
School/Faculty:Colleges (2008 onwards) > College of Engineering & Physical Sciences
Department:School of Civil Engineering
Subjects:TP Chemical technology
TA Engineering (General). Civil engineering (General)
Institution:University of Birmingham
ID Code:1453
This unpublished thesis/dissertation is copyright of the author and/or third parties. The intellectual property rights of the author or third parties in respect of this work are as defined by The Copyright Designs and Patents Act 1988 or as modified by any successor legislation. Any use made of information contained in this thesis/dissertation must be in accordance with that legislation and must be properly acknowledged. Further distribution or reproduction in any format is prohibited without the permission of the copyright holder.
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